Two choices for the third layer lead to two different close-packed lattice types |
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date: 2-5-2020
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Date: 28-4-2020
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Date: 28-4-2020
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Now consider what happens when we lay down a third layer of atoms. These will fit into the void spaces within the B-layer. As before, there are two sets of these positions, but unlike the case described above, they are not equivalent.
The atoms in the third layer are represented by open blue circles in order to avoid obscuring the layers underneath. In the illustration on the left, this third layer is placed on the B-layer at locations that are directly above the atoms of the A-layer, so our third layer is just a another A layer. If we add still more layers, the vertical sequence A-B-A-B-A-B-A... repeats indefinitely.
In the diagram on the right above, the blue atoms have been placed above the white (unoccupied) void spaces in layer A. Because this third layer is displaced horizontally (in our view) from layer A, we will call it layer C. As we add more layers of atoms, the sequence of layers is A-B-C-A-B-C-A-B-C..., so we call it ABC packing.
These two diagrams that show exploded views of the vertical stacking further illustrate the rather small fundamental difference between these two arrangements— but, as you will see below, they have widely divergent structural consequences. Note the opposite orientations of the A and C layers
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