 
					
					
						Pressure, Temperature and RMS Speed					
				 
				
					
						 المؤلف:  
						Professor John W. Norbury
						 المؤلف:  
						Professor John W. Norbury					
					
						 المصدر:  
						ELEMENTARY MECHANICS & THERMODYNAMICS
						 المصدر:  
						ELEMENTARY MECHANICS & THERMODYNAMICS					
					
						 الجزء والصفحة:  
						p  230
						 الجزء والصفحة:  
						p  230					
					
					
						 1-1-2017
						1-1-2017
					
					
						 1884
						1884					
				 
				
				
				
				
				
				
				
				
				
			 
			
			
				
				Pressure, Temperature and RMS Speed
Now consider our first kinetic theory problem. Imagine a gas, consisting of n moles being confined to a cubical box of volume V. ''What is the connection between the pressure p exerted by the gas on the walls and the speeds of the molecules?" Pressure is defined as Force divided by Area or  where
 where  . Using Newtonian Mechanics, shows that
. Using Newtonian Mechanics, shows that

where n is the number of moles, M is the mass of 1 mole of the gas (so that nM is the total mass of the gas), vRMS is the average speed of the molecules and V is the volume of the gas. The above equation is derived purely from applying Newtonian mechanics to the individual molecules.  Now by comparing to the ideal gas law pV = nRT or  we must have
we must have  or
or

which shows that the temperature T is related to the speed of molecules!
As shown the speed of molecules at room temperature is very large; about 500 m/sec for air (about 1000 mph).
				
				
					
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					 الاكثر قراءة في  الفيزياء الكيميائية					
					
				 
				
				
					
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